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Establishing a nonzero measurement of the electron Electric Dipole Moment (eEDM) has long been a fundamental pursuit in atomic, molecular and optical physics, offering possible insights into new physics beyond the Standard Model. In this regard, lead monofluoride (PbF) has emerged as a potential candidate for measuring eEDM primarily due to its suitable properties such as the strong internal effective electric field, and eEDM-sensitive ground state with large Ω-doubling and small magnetic g factor. In the present work, we realized the production of a buffer-gas-cooled PbF molecular beam and characterized its high-resolution spectroscopy in the B 2Σ+(υ’=0) ← X1 2Π1/2(υ = 0) transition, including both direct absorption and laser-induced fluorescence spectroscopy. A highly concentrated beam of PbF molecules is obtained with a central forward velocity of 223 ± 17 m/s, while 81, 66 and 24 hyperfine-structure-resolved spectral lines with a frequency accuracy of 40 MHz have been assigned respectively for 208PbF, 207PbF and 206PbF isotopologues. The hyperfine constants due to the 19F nucleus (A∥ and A⊥) of the B state are reported for the first time, and those of the 207Pb nucleus have been also updated. Such a cryogenic molecular beam of PbF in association with its hyperfine-structure-resolved spectral atlas of the B 2Σ+(υ’=0) ← X1 2Π1/2(υ = 0) transition will be essential in developing sensitive detection schemes towards the eEDM measurement. 

The synthesis of biaryl compounds by employing carboxylic acids as double aryl group donors is reported. 

A series of bimetallic carbene-metal-amide (cMa) complexes have been prepared with bridging biscarbene ligands to serve as a model for the design of luminescent materials with large oscillator strengths and small energy differences between the singlet and triplet states (dE ST). The complexes have a general structure (R2N)Au(:carbene—carbene:)Au(NR2). The bimetallic complexes show solvation-dependent absorption and emission that is analyzed in detail. It is found that the molar absorptivity of the bimetallic complexes is correlated with the energy barrier to rotation of the metal-ligand bond. The bimetallic cMa complexes also exhibit short emission lifetimes (t = 200-300 ns) with high photoluminescence efficiencies (PL >95%). The radiative rates of bimetallic cMa complexes are 3 to 4 times faster than that of the corresponding monometallic complexes. Analysis of temperature-dependent luminescence data indicates that the lifetime for the singlet state (τ_(S_1 )) of bimetallic cMa complexes are near 12 ns with a dE ST of 40 50 meV. The presented compounds provide a general design for cMa complexes to achieve small values for dE ST while retaining high radiative rates. Solution processed OLEDs made using two of the complexes as luminescent dopants show high efficiency and low roll-off at high luminance. 

Abstract Given a family$$\mathcal{F}$$of bipartite graphs, theZarankiewicz number$$z(m,n,\mathcal{F})$$is the maximum number of edges in an$$m$$by$$n$$bipartite graph$$G$$that does not contain any member of$$\mathcal{F}$$as a subgraph (such$$G$$is called$$\mathcal{F}$$-free). For$$1\leq \beta \lt \alpha \lt 2$$, a family$$\mathcal{F}$$of bipartite graphs is$$(\alpha,\beta )$$-smoothif for some$$\rho \gt 0$$and every$$m\leq n$$,$$z(m,n,\mathcal{F})=\rho m n^{\alpha -1}+O(n^\beta )$$. Motivated by their work on a conjecture of Erdős and Simonovits on compactness and a classic result of Andrásfai, Erdős and Sós, Allen, Keevash, Sudakov and Verstraëte proved that for any$$(\alpha,\beta )$$-smooth family$$\mathcal{F}$$, there exists$$k_0$$such that for all odd$$k\geq k_0$$and sufficiently large$$n$$, any$$n$$-vertex$$\mathcal{F}\cup \{C_k\}$$-free graph with minimum degree at least$$\rho (\frac{2n}{5}+o(n))^{\alpha -1}$$is bipartite. In this paper, we strengthen their result by showing that for every real$$\delta \gt 0$$, there exists$$k_0$$such that for all odd$$k\geq k_0$$and sufficiently large$$n$$, any$$n$$-vertex$$\mathcal{F}\cup \{C_k\}$$-free graph with minimum degree at least$$\delta n^{\alpha -1}$$is bipartite. Furthermore, our result holds under a more relaxed notion of smoothness, which include the families$$\mathcal{F}$$consisting of the single graph$$K_{s,t}$$when$$t\gg s$$. We also prove an analogous result for$$C_{2\ell }$$-free graphs for every$$\ell \geq 2$$, which complements a result of Keevash, Sudakov and Verstraëte. 

This study presents the synthesis and characterization of two spirobifluorenyl derivatives substituted with either triphenylmethyl (SB-C) or triphenylsilyl (SB-Si) moieties for use as host materials in phosphorescent organic light-emitting diodes (PHOLED). Both molecules have similar high triplet energies and large energy gaps. Blue Ir(tpz)3 and green Ir(ppy)3 phosphorescent devices were fabricated using these materials as hosts. Surprisingly, SB-Si demonstrated superior charge-transporting ability compared to SB-C, despite having similar energies for their valence orbitals. In particular, SB-Si proved to be a highly effective host for both blue and green devices, resulting in maximum efficiencies of 12.6% for the Ir(tpz)3 device and 9.6% for the Ir(ppy)3 device. These results highlight the benefits of appending the triphenylsilyl moiety onto host materials and underscore the importance of considering the morphology of hosts in the design of efficient PHOLEDs.